The libxml extension is enabled by default, although it may be disabled with --without-libxml.
   PHP uses pkg-config to select the right library file, header files,
   and compile flags to use for libxml2.
   To ensure that the desired version of libxml2 is selected,
   the PKG_CONFIG_PATH environment variable may
   be used to control the search path for pkg-config prior to running the configure script:
   
PKG_CONFIG_PATH="/path/to/libxml2/prefix/lib/pkgconfig:/lib/pkgconfig"
